Ecology and Environment ›› 2024, Vol. 33 ›› Issue (2): 282-290.DOI: 10.16258/j.cnki.1674-5906.2024.02.012
• Research Article [Environmental Sciences] • Previous Articles Next Articles
CONG Xin(), CAO Ping, WANG Xiaobo
Received:
2023-10-31
Online:
2024-02-18
Published:
2024-04-03
作者简介:
丛鑫(1976年生)女,教授,博士,研究方向为土壤环境化学和生态修复。E-mail: congxin1800@163.com
基金资助:
CLC Number:
CONG Xin, CAO Ping, WANG Xiaobo. Degradation of Pentachlorobiphenyl in Soil Using Persulfate Activated by Biochar-supported Nano Zero-valent Iron[J]. Ecology and Environment, 2024, 33(2): 282-290.
丛鑫, 曹平, 王晓博. 生物炭负载纳米铁活化过硫酸盐去除土壤中的五氯联苯[J]. 生态环境学报, 2024, 33(2): 282-290.
Add to citation manager EndNote|Ris|BibTeX
URL: https://www.jeesci.com/EN/10.16258/j.cnki.1674-5906.2024.02.012
水平 | 实验因素 | ||
---|---|---|---|
A: PS浓度/(mol·L−1) | B: 温度/℃ | C: pH | |
−1 | 0.05 | 25 | 1 |
0 | 0.20 | 35 | 3 |
1 | 0.35 | 45 | 5 |
Table 1 The factors and levels of response surface optimization test
水平 | 实验因素 | ||
---|---|---|---|
A: PS浓度/(mol·L−1) | B: 温度/℃ | C: pH | |
−1 | 0.05 | 25 | 1 |
0 | 0.20 | 35 | 3 |
1 | 0.35 | 45 | 5 |
实验序号 | PS浓度/(mol·L−1) | 温度/℃ | pH | 去除率/% | 实验序号 | PS浓度/(mol·L−1) | 温度/℃ | pH | 去除率/% | |
---|---|---|---|---|---|---|---|---|---|---|
1 | 0.05 | 25 | 3 | 20.62 | 10 | 0.20 | 45 | 1 | 56.64 | |
2 | 0.35 | 25 | 3 | 45.79 | 11 | 0.20 | 25 | 5 | 38.61 | |
3 | 0.05 | 45 | 3 | 50.42 | 12 | 0.20 | 45 | 5 | 58.72 | |
4 | 0.35 | 45 | 3 | 61.81 | 13 | 0.20 | 35 | 3 | 59.68 | |
5 | 0.05 | 35 | 1 | 24.49 | 14 | 0.20 | 35 | 3 | 59.15 | |
6 | 0.35 | 35 | 1 | 36.23 | 15 | 0.20 | 35 | 3 | 58.32 | |
7 | 0.05 | 35 | 5 | 18.85 | 16 | 0.20 | 35 | 3 | 60.69 | |
8 | 0.35 | 35 | 5 | 46.78 | 17 | 0.20 | 35 | 3 | 60.33 | |
9 | 0.20 | 25 | 1 | 32.47 |
Table 2 Experiment design and results of response surface
实验序号 | PS浓度/(mol·L−1) | 温度/℃ | pH | 去除率/% | 实验序号 | PS浓度/(mol·L−1) | 温度/℃ | pH | 去除率/% | |
---|---|---|---|---|---|---|---|---|---|---|
1 | 0.05 | 25 | 3 | 20.62 | 10 | 0.20 | 45 | 1 | 56.64 | |
2 | 0.35 | 25 | 3 | 45.79 | 11 | 0.20 | 25 | 5 | 38.61 | |
3 | 0.05 | 45 | 3 | 50.42 | 12 | 0.20 | 45 | 5 | 58.72 | |
4 | 0.35 | 45 | 3 | 61.81 | 13 | 0.20 | 35 | 3 | 59.68 | |
5 | 0.05 | 35 | 1 | 24.49 | 14 | 0.20 | 35 | 3 | 59.15 | |
6 | 0.35 | 35 | 1 | 36.23 | 15 | 0.20 | 35 | 3 | 58.32 | |
7 | 0.05 | 35 | 5 | 18.85 | 16 | 0.20 | 35 | 3 | 60.69 | |
8 | 0.35 | 35 | 5 | 46.78 | 17 | 0.20 | 35 | 3 | 60.33 | |
9 | 0.20 | 25 | 1 | 32.47 |
方差来源 | 模型 | A | B | C | AB | AC | BC | 失拟项 |
---|---|---|---|---|---|---|---|---|
平方和 | 3645.38 | 726.38 | 1014.75 | 21.55 | 47.47 | 65.53 | 4.12 | 2.87 |
自由度 | 9 | 1 | 1 | 1 | 1 | 1 | 1 | 3 |
均方 | 405.04 | 726.38 | 1014.75 | 21.55 | 47.47 | 65.53 | 4.12 | 0.9583 |
F值 | 440.43 | 789.85 | 1103.42 | 23.43 | 51.62 | 71.25 | 4.48 | 1.08 |
P值 | <0.0001 | <0.0001 | <0.0001 | 0.0019 | 0.0002 | <0.0001 | 0.0721 | 0.4538 |
显著性 | 极显著 | 极显著 | 极显著 | 极显著 | 极显著 | 极显著 | 不显著 | 不显著 |
Table 3 The variance analysis of regression model
方差来源 | 模型 | A | B | C | AB | AC | BC | 失拟项 |
---|---|---|---|---|---|---|---|---|
平方和 | 3645.38 | 726.38 | 1014.75 | 21.55 | 47.47 | 65.53 | 4.12 | 2.87 |
自由度 | 9 | 1 | 1 | 1 | 1 | 1 | 1 | 3 |
均方 | 405.04 | 726.38 | 1014.75 | 21.55 | 47.47 | 65.53 | 4.12 | 0.9583 |
F值 | 440.43 | 789.85 | 1103.42 | 23.43 | 51.62 | 71.25 | 4.48 | 1.08 |
P值 | <0.0001 | <0.0001 | <0.0001 | 0.0019 | 0.0002 | <0.0001 | 0.0721 | 0.4538 |
显著性 | 极显著 | 极显著 | 极显著 | 极显著 | 极显著 | 极显著 | 不显著 | 不显著 |
[1] |
CHEN X Q, MURUGANANTHAN M, ZHANG Y R, 2016. Degradation of p-Nitrophenol by thermally activated persulfate in soil system[J]. Chemical Engineering Journal, 283: 1357-1365.
DOI URL |
[2] |
DANISH M, GU X G, LU S G, et al., 2017. Efficient transformation of trichloroethylene activated through sodium percarbonate using heterogeneous zeolite supported nano zero valent iron-copper bimetallic composite[J]. Chemical Engineering Journal, 308: 396-407.
DOI URL |
[3] |
DOMINGUEZ C M, RODRIGUEZ V, MONTERO E, et al., 2020. Abatement of dichloromethane using persulfate activated by alkali: A kinetic study[J]. Separation and Purification Technology, 241: 116679.
DOI URL |
[4] |
DONG H R, NING Q, LI L, et al., 2020. A comparative study on the activation of persulfate by bare and surface stabilized nanoscale zero-valent iron for the removal of sulfamethazine[J]. Separation and Purification Technology, 230: 115869.
DOI URL |
[5] |
DU J K, BAO J G, LU C H, et al., 2016. Reductive sequestration of chromate by hierarchical FeS@Fe(0) particles[J]. Water Research, 102: 73-81.
DOI PMID |
[6] |
FU H C, MA S L, ZHAO P, et al., 2019. Activation of peroxymonosulfate by graphitized hierarchical porous biochar and MnFe2O4 magnetic nanoarchitecture for organic pollutants degradation: Structure dependence and mechanism[J]. Chemical Engineering Journal, 360: 157-170.
DOI URL |
[7] |
GUANG Y H, MA J, LI X C, et al., 2011. Influence of pH on the formation of sulfate and hydroxyl radicals in the UV/peroxymonosulfate system[J]. Environmental Science & Technology, 45(21): 9308-9314.
DOI URL |
[8] |
GUO Y G, HUANG W L, CHEN B, et al., 2017. Removal of tetracycline from aqueous solution by MCM-41-zeolite A loaded nano zero valent iron: synthesis, characteristic, adsorption performance and mechanism[J]. Journal of Hazardous Materials, 339: 22-32.
DOI PMID |
[9] |
HUANG Y H, ZHANG T C, 2006. Reduction of nitrobenzene and formation of corrosion coatings in zerovalent iron systems[J]. Water Research, 40(16): 3075-3082.
DOI PMID |
[10] |
JI Y F, FERRONATO C, SALVADOR A, et al., 2014. Degradation of ciprofloxacin and sulfamethoxazole by ferrous-activated persulfate: Implications for remediation of groundwater contaminated by antibiotics[J]. Science of the Total Environment, 472: 800-808.
DOI URL |
[11] | KONG F L, WANG J R, HOU W H, et al., 2023. Influence of modified biochar supported sulfidation of nano-zero-valent-iron (S-nZVI/BC) on nitrate removal and greenhouse gas emission in constructed wetland[J]. Joumal of Environmental Sciences, 125: 568-581. |
[12] | LE C, WU J H, LI P, et al., 2011. Decolorization of anthraquinone dye reactive blue 19 by the combination of persulfate and zero-valent iron[J]. Water Science & Technology, 64(3): 754-759. |
[13] |
LI H H, ZHU F, HE S Y, 2019. The degradation of decabromodiphenyl ether in the e-waste site by biochar supported nanoscale zero-valent iron/ persulfate[J]. Ecotoxicology and Environmental Safety, 183: 109540.
DOI URL |
[14] |
NIE M H, YAN C X, LI M, et al., 2015. Degradation of chloramphenicol by persulfate activated by Fe2+ and zerovalent iron[J]. Chemical Engineering Journal, 279: 507-515.
DOI URL |
[15] |
OH S Y, KIM H W, PARK J M, et al., 2009. Oxidation of polyvinyl alcohol by persulfate activated with heat, Fe2+, and zero-valent iron[J]. Journal of Hazardous Materials, 168(1): 346-351.
DOI URL |
[16] |
OUYANG D, YAN J C, QIAN L B, et al., 2017. Degradation of 1,4-dioxane by biochar supported nano magnetite particles activating persulfate[J]. Chemosphere, 184: 609-617.
DOI PMID |
[17] |
PENG H J, ZHANG W, LIU L, et al., 2017. Degradation performance and mechanism of decabromodiphenyl ether (BDE209) by ferrous- activated persulfate in spiked soil[J]. Chemical Engineering Journal, 307: 750-755.
DOI URL |
[18] |
SU H J, FANG Z Q, TSANG P E, et al., 2016. Stabilisation of nanoscale zero-valent iron with biochar for enhanced transport and in-situ remediation of hexavalent chromium in soil[J]. Environmental Pollution, 214: 94-100.
DOI PMID |
[19] | WANG B, ZHU C, AI D, et al., 2021. Activation of persulfate by green nano-zero-valent iron-loaded biochar for the removal of p-nitrophenol: Performance, mechanism and variables effects[J]. Journal of Hazardous Materials, 417(1): 26106. |
[20] |
WENG X L, OWENS G, CHEN Z L, 2020. Synergetic adsorption and Fenton-like oxidation for simultaneous removal of ofloxacin and enrofloxacin using green synthesized Fe NPs[J]. Chemical Engineering Journal, 382: 122871.
DOI URL |
[21] |
XIA X H, ZHU F Y, LI J N, et al., 2020. A Review Study on Sulfate- Radical-Based Advanced Oxidation Processes for Domestic/Industrial Wastewater Treatment: Degradation, Efficiency, and Mechanism[J]. Frontiers in Chemistry, 8: 592056.
DOI URL |
[22] |
XU H B, ZHAO D Y, LI Y J, et al., 2014. Enhanced degradation of ortho-nitrochlorobenzene by the combined system of zero-valent iron reduction and persulfate oxidation in soil[J]. Environmental Science and Pollution Research, 21: 5132-5140.
DOI URL |
[23] |
XU J, WANG X R, PAN F, et al., 2018. Synthesis of the mesoporous carbon-nano-zero-valent iron composite and activation of sulfite for removal of organic pollutants[J]. Chemical Engineering Journal, 353: 542-549.
DOI URL |
[24] |
XUE H H, GAO S Y, ZHENG N, et al., 2019. Degradation of norfloxacin in aqueous solution with UV/peroxydisulfate[J]. Water Science and Technology, 79(12): 2387-2394.
DOI PMID |
[25] |
YEN C H, CHEN K F, KAO C M, et al., 2011. Application of persulfate to remediate petroleum hydrocarbon-contaminated soil: Feasibility and comparison with common oxidants[J]. Journal of hazardous materials, 186(2-3): 2097-2012.
DOI URL |
[26] |
ZHU F, WU Y Y, LIANG Y K et al., 2020. Degradation mechanism of norfloxacin in water using persulfate activated by BC@nZVI/Ni[J]. Chemical Engineering Journal, 389: 124276.
DOI URL |
[27] | 昌盛, 白云松, 涂响, 等, 2022. 北江中上游地表水和沉积物中PAHs和PCBs污染特征和风险评估[J]. 环境科学, 43(12): 5534-5546. |
CHANG S, BAI Y S, TU X, et al., 2022. Pollution characteristics and risk assessment of PAHs and PCBs in surface water and sediments in middle and upper reaches of Beijing River[J]. Environmental Science, 43(12): 5534-5546. | |
[28] | 黄开友, 申英杰, 王晓岩, 等, 2020. 生物炭负载纳米零价铁制备及修复六价铬污染土壤技术研究进展[J]. 环境工程, 38(11): 203-210. |
HUANG Y K, SHEN Y J, WANG X Y, et al., 2020. Review on preparation of bio-carbon loaded nano zero-valent iron and its application in remediating Cr(Ⅵ)-contaminated soil[J]. Environmental Engineering, 38(11): 203-210. | |
[29] | 李丹琼, 2023. 生物炭负载纳米零价铁活化过硫酸盐降解水中菲的模拟研究[D]. 北京: 中国矿业大学. |
LI D Q, 2022. Simulation study on degradation of phenanthrene in groundwater by persulfate activated with biochar-supported nano zero-valent iron[D]. Beijing: China University of Mining and Technology. | |
[30] | 李璐玮, 祝方, 马少云, 等, 2017. 响应面分析法优化纳米零价铁铜双金属修复土壤浸提液中Cr(Ⅵ)[J]. 环境工程学报, 11(1): 608-612. |
LI L W, ZHU F, MA S Y, et al., 2017. Optimization of remediation of Cr(Ⅵ) contaminated soil leachate by nano-zero valent iron/copper by response surface methodological analysis[J]. Chinese Journal of Environmental Engineering, 11(1): 608-612. | |
[31] | 李永涛, 罗进, 岳东, 2017. 热活化过硫酸盐氧化修复柴油污染土壤[J]. 环境污染与防治, 39(10): 1143-1146. |
LI Y T, LUO J, YUE D, 2017. Thermo activated persulfate oxidation for remediation of diesel oil contaminated soil[J]. Environmental Pollution and Control, 39(10):1143-1146. | |
[32] | 刘勇, 2018. 桉树叶提取液绿色合成纳米铁材料及水中Cr(Ⅵ)的去除研究[D]. 福州: 福建师范大学. |
LIU Y, 2018. Green synthesis of iron-based nanoparticles by eucalyptus leaf and used to remove Cr(Ⅵ) from aqueous solution[D]. Fuzhou: Fujian Normal University. | |
[33] | 宁沁, 2020. 表面改性纳米零价铁在不同反应体系中去除有机污染物的效能与机制研究[D]. 长沙: 湖南大学. |
NING Q, 2020. Efficiency and mechanisms of surface-modified nanoscale zero-valent iron for the removal of organic pollutants in different reaction systems[D]. Changsha: Hunan University. | |
[34] | 宋艳, 林道辉, 2022. 过硫酸盐对电动-铁/碳复合材料联合修复多氯联苯污染土壤的强化作用[J]. 环境科学学报, 42(5): 435-443. |
SONG Y, LIN D H, 2022. The enhancement of persulfate on the electrokinetic-iron/carbon composite co-remediation of PCBs- contaminated soil[J]. Acta Scientiae Circumstantiae, 42(5): 435-443. | |
[35] | 宿程远, 李伟光, 刘兴哲, 等, 2013. 响应曲面法优化制备改性海泡石负载纳米铁材料的试验研究[J]. 环境科学学报, 33(4): 985-990. |
SU C Y, LI W G, LIU X Z, et al., 2013. Optimal preparation conditions of sepiolite-supported nanoscale iron using response surface methodology[J]. Acta Scientiae Circumstantiae, 33(4): 985-990. | |
[36] | 魏海江, 杨兴伦, 叶茂, 等, 2014. 活化过硫酸钠氧化法修复DDTs污染场地土壤研究[J]. 土壤, 46(3): 504-511. |
WEI H J, YANG X L, YE M, et al., 2014. Application of activated persulfate oxidation method in degradating DDT in field contaminated soil[J]. Soils, 46(3): 504-511. | |
[37] | 文勤亮, 张瀚文, 许海波, 等, 2014. 零价铁还原-过硫酸盐氧化联合降解土壤中对硝基氯苯的研究[J]. 南京农业大学学报, 37(6): 111-118. |
WEN Q L, ZHANG H W, XU H B, et al., 2014. Degradation of p-nigtrochlorobenzene in soil by zero-valent iron activated persulfate[J]. Journal of Nanjing Agricultural University, 37(6): 111-118. | |
[38] | 张羽, 高春阳, 陈昌照, 等, 2019. 零价铁活化过硫酸钠体系降解污染土壤中的多环芳烃[J]. 环境工程学报, 13(4): 955-962. |
ZHANG Y, GAO C Y, CHEN C Z, et al., 2019. Degradation of PAHs in contaminated soil by zero valent iron activated sodium persulfate system[J]. Chinese Journal of Environmental Engineering, 13(4): 955-962. | |
[39] | 张志, 2010. 中国大气和土壤中多氯联苯空间分布特征及规律研究[D]. 哈尔滨: 哈尔滨工业大学. |
ZHANG Z, 2010. Polychlorinated biphenyls in Chinese air and surface soil: Spatial distribution characteristics and their inherent causes[D]. Harbin: Harbin Institute of Technology. |
[1] | LI Gaofan, XU Wenzhuo, WEI Haoming, YAN Zaisheng, YOU Jia, JIANG Helong, HUANG Juan. Preparation of 3D Porous Biochar Adsorbent and Its Adsorption Behavior for Phenanthrene [J]. Ecology and Environment, 2024, 33(2): 261-271. |
[2] | ZHAO Weibin, TANG Li, WANG Song, LIU Lingling, WANG Shufeng, XIAO Jiang, CHEN Guangcai. Improvement Effect of Two Biochars on Coastal Saline-Alkaline Soil [J]. Ecology and Environment, 2023, 32(4): 678-686. |
[3] | LI Zhuoxuan, PENG Ziran, HE Wenhui, WEI Ruilu, GAO Linxi. Response Surface Optimization and Adsorption Mechanism of Sheep Manure Charcoal on Nitrogen and Phosphorus Adsorption Conditions [J]. Ecology and Environment, 2023, 32(12): 2216-2227. |
[4] | ZHAO Dandan, LI Wenjian, JIANG Lixia, SHAN Rui, CHEN Dezhen, YUAN Haoran, CHEN Yong. Progress in the Preparation and Performance of Biochar-based Photocatalysts [J]. Ecology and Environment, 2023, 32(11): 2019-2029. |
[5] | SU Dan, LUO Qiaobing, DONG Yushan, YANG Caixia, WANG Xin. Strengthening Effect of Mixed Biochar on Microbial Remediation of PAHs Contaminated Soil in Cold Areas [J]. Ecology and Environment, 2023, 32(11): 1942-1951. |
[6] | CHEN Guihong. Remediation of Cadmium Contaminated Soil by Sulfur/Silicon Doped Biochar [J]. Ecology and Environment, 2023, 32(10): 1854-1860. |
[7] | WANG Jie, SHAN Yan, MA Lan, SONG Yanjing, WANG Xiangyu. Effects of Straw and Biochar Synergistic Returning on the Improvement of Salt-affected Soil in the Yellow River Delta [J]. Ecology and Environment, 2023, 32(1): 90-98. |
[8] | YOU Hongjian, ZHANG Wenwen, LAN Zhengfang, MA Lan, ZHANG Baodi, MU Xiaokun, LI Wenhui, CAO Yune. Effects of Earthworm in-situ Composting and Biochar on Cucumber Root-knot Nematodes and Rhizosphere Microorganisms [J]. Ecology and Environment, 2023, 32(1): 99-109. |
[9] | LI Xiaohui, AI Xianbin, LI Liang, WANG Xiyang, XIN Zaijun, SUN Xiaoyan. Study on Passivation Effects of New Modified Rice Husk Biochar Materials on Cadmium Contaminated Soil [J]. Ecology and Environment, 2022, 31(9): 1901-1908. |
[10] | FANG Xianbao, ZHANG Zhijun, LAI Yangqing, YE Mai, DIAO Zenghui. Remediation of Heavy Metals Cr and Cd in Soil by A Novel Sludge-derived Biochar [J]. Ecology and Environment, 2022, 31(8): 1647-1656. |
[11] | TAO Ling, HUANG Lei, ZHOU Yilei, LI Zhongxing, REN Jun. Influences of Biochar Prepared by Co-pyrolysis with Sludge and Attapulgite on Bioavailability and Environmental Risk of Heavy Metals in Mining Soil [J]. Ecology and Environment, 2022, 31(8): 1637-1646. |
[12] | QIAN Lianwen, YU Tiantian, LIANG Xujun, WANG Yixiang, CHEN Yongshan. Stability of Biochar after Application for 5 Years in the Amendment of Acidified Tea Garden Soil [J]. Ecology and Environment, 2022, 31(7): 1442-1447. |
[13] | ZHANG Huiqi, LI Zizhong, QI Yan. Effects of Corn Straw-based Biochar Amount on Pores and Water Holding Capacity of Sandy Soil [J]. Ecology and Environment, 2022, 31(6): 1272-1277. |
[14] | DENG Xiao, WU Chunyuan, YANG Guisheng, LI Yi, LI Qinfen. Improvement Effect of Coconut-shell Biochar on Coastal Soil in Hainan [J]. Ecology and Environment, 2022, 31(4): 723-731. |
[15] | CHENG Wenyuan, LI Fayun, LÜ Jianhua, LIN Meixia, WANG Wei. Sorption Characteristics of Polycyclic Aromatic Hydrocarbons Phenanthrene on Sunflower Straw Biochar Modified with Alkali [J]. Ecology and Environment, 2022, 31(4): 824-834. |
Viewed | ||||||
Full text |
|
|||||
Abstract |
|
|||||
Copyright © 2021 Editorial Office of ACTA PETROLEI SINICA
Address:No. 6 Liupukang Street, Xicheng District, Beijing, P.R.China, 510650
Tel: 86-010-62067128, 86-010-62067137, 86-010-62067139
Fax: 86-10-62067130
Email: syxb@cnpc.com.cn
Support byBeijing Magtech Co.ltd, E-mail:support@magtech.com.cn