Ecology and Environment ›› 2020, Vol. 29 ›› Issue (2): 411-420.DOI: 10.16258/j.cnki.1674-5906.2020.02.024
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JIN Tuo1,3(), XUE Yinghao1,2,*(
), ZHANG Mingming4, ZHOU Tao5, LIU Hongjin6, ZHANG Kai7, XI Bin1
Received:
2019-12-24
Online:
2020-02-18
Published:
2020-04-01
Contact:
XUE Yinghao
靳拓1,3(), 薛颖昊1,2,*(
), 张明明4, 周涛5, 刘宏金6, 张凯7, 习斌1
通讯作者:
薛颖昊
作者简介:
靳拓(1989年生),男,助理研究员,博士,主要从事农业环保工作。E-mail: jintuo273@126.com
基金资助:
CLC Number:
JIN Tuo, XUE Yinghao, ZHANG Mingming, ZHOU Tao, LIU Hongjin, ZHANG Kai, XI Bin. Research Advances in Regulations, Standards and Recovery of Mulch Film[J]. Ecology and Environment, 2020, 29(2): 411-420.
靳拓, 薛颖昊, 张明明, 周涛, 刘宏金, 张凯, 习斌. 国内外农用地膜使用政策、执行标准与回收状况[J]. 生态环境学报, 2020, 29(2): 411-420.
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URL: https://www.jeesci.com/EN/10.16258/j.cnki.1674-5906.2020.02.024
材料 Materials | 原料 Raw material | 合成方式 Compound method | 预估降解率 Estimated degradation rate |
---|---|---|---|
Cellulose | 生物基 Biology base | 生物合成 Biosynthesis | 高 High |
PBAT | 烃类 Hydrocarbon | 化学合成 Chemosynthesis | 中低 Lower middle |
PBS | 烃类 Hydrocarbon | 化学合成 Chemosynthesis | 中低 Lower middle |
PBSA | 烃类 Hydrocarbon | 化学合成 Chemosynthesis | 中低 Lower middle |
PCL | 烃类 Hydrocarbon | 化学合成 Chemosynthesis | 中 Middle |
PHA | 生物基 Biology base | 生物合成 Biosynthesis | 中高 Higher middle |
PLA | 生物基 Biology base | 生物合成和化学合成 Biosynthesis and chemosynthesis | 低 Low |
Sucrose | 生物基 Biology base | 生物合成 Biosynthesis | 高 High |
TPS/Starch | 生物基 Biology base | 生物合成 Biosynthesis | 高 High |
Table 1 Common biodegradable polymers, synthetic sources and their estimated degradation rate in soil
材料 Materials | 原料 Raw material | 合成方式 Compound method | 预估降解率 Estimated degradation rate |
---|---|---|---|
Cellulose | 生物基 Biology base | 生物合成 Biosynthesis | 高 High |
PBAT | 烃类 Hydrocarbon | 化学合成 Chemosynthesis | 中低 Lower middle |
PBS | 烃类 Hydrocarbon | 化学合成 Chemosynthesis | 中低 Lower middle |
PBSA | 烃类 Hydrocarbon | 化学合成 Chemosynthesis | 中低 Lower middle |
PCL | 烃类 Hydrocarbon | 化学合成 Chemosynthesis | 中 Middle |
PHA | 生物基 Biology base | 生物合成 Biosynthesis | 中高 Higher middle |
PLA | 生物基 Biology base | 生物合成和化学合成 Biosynthesis and chemosynthesis | 低 Low |
Sucrose | 生物基 Biology base | 生物合成 Biosynthesis | 高 High |
TPS/Starch | 生物基 Biology base | 生物合成 Biosynthesis | 高 High |
标准号 Standard number | 机构 Institution | 名称 Name | 评估目标 Assessment objectives |
---|---|---|---|
ISO 16929 | ISO | Plastics-Determination of the degree of disintegration of plastic materials under defined composting conditions in a pilot-scale test | Determine the degree of disintegration of plastic materials in a pilot-scale aerobic composting test under defined conditions |
ASTM D6400-12 | ASTM | Standard specification for labelling of plastics designed to be aerobically composted in municipal or industrial facilities | Determine if plastics will compost satisfactorily, and establish requirements for identifying items made from plastics or polymers, as “compostable in aerobic municipal and industrial composting facilities” |
ASTM D5338-15 | ASTM | Standard test method for determining aerobic biodegradation of plastic materials under controlled composting conditions, incorporating thermophilic temperatures | Determines the degree and rate of aerobic biodegradation of plastic materials on exposure to a controlled-composting environment under laboratory conditions, at thermophilic temperatures |
ASTM D6868-19 | ASTM | Standard specification for labelling of end items that incorporate plastics and polymers as coatings or additives with paper and other substrates designed to be aerobically composted in municipal or industrial facilities | Determine if end items (including packaging) which use plastics and polymers as coatings or binders will compost satisfactorily, in large scale aerobic municipal or industrial composting where maximum throughput is a high priority and where intermediate stages of plastic biodegradation must not be visible to the end user for aesthetic reasons |
ASTM D6954-18 | ASTM | Standard guide for exposing and testing plastics that degrade in the environment by a combination of oxidation and biodegradation | Compare and rank the controlled laboratory rates of degradation and degree of physical property losses of polymers by thermal and photooxidation processes as well as the biodegradation and ecological impacts in defined applications and disposal environments after degradation |
ASTM D5988-18 | ASTM | Standard test method for determining aerobic biodegradation of plastic materials in soil | Under laboratory conditions, determine the degree and rate of aerobic biodegradation of plastic materials, including formulation additives, in contact with soil |
ASTM D5526-18 | ASTM | Standard test method for determining anaerobic biodegradation of plastic materials under accelerated landfill conditions | Determine the degree and rate of anaerobic biodegradation of plastic materials in an accelerated-landfill test environment |
ASTM D7475-11 | ASTM | Standard test method for determining the aerobic degradation and anaerobic biodegradation of plastic materials under accelerated bioreactor landfill conditions | Determine the degree and rate of aerobic degradation (as indicated by loss of tensile strength, molecular weight, possibly resulting in disintegration and fragmentation) and anaerobic biodegradation of plastic materials in an accelerated bioreactor landfill test environment |
ASTM D6691-17 | ASTM | Standard test method for determining aerobic biodegradation of plastic materials in the marine environment by a defined microbial consortium or natural sea water Inoculum | Under controlled laboratory conditions, assess the rate and degree of aerobic biodegradation of plastics exposed to marine microorganisms |
ASTM D5511-18 | ASTM | Standard test method for determining anaerobic biodegradation of plastic materials under high-solids anaerobic-digestion conditions | Determine the rate and degree of anaerobic biodegradability of plastic products when placed in a high-solids anaerobic digester |
ASTM D7444-18a | ASTM | Standard practice for heat and humidity aging of oxidatively degradable plastics | Test the oxidative degradation characteristics of plastics that degrade in the environment under atmospheric pressure and thermal and humidity simulations |
ASTM WK41850 | ASTM | New Test Method for Determining the rate and extent of plastics biodegradation in an anaerobic laboratory environment under accelerated conditions | Laboratory assessment of the extent and rate of biodegradation of plastics in a simulated landfill environment |
Table 2 International and American standards for evaluating degradability of plastics under composting conditions
标准号 Standard number | 机构 Institution | 名称 Name | 评估目标 Assessment objectives |
---|---|---|---|
ISO 16929 | ISO | Plastics-Determination of the degree of disintegration of plastic materials under defined composting conditions in a pilot-scale test | Determine the degree of disintegration of plastic materials in a pilot-scale aerobic composting test under defined conditions |
ASTM D6400-12 | ASTM | Standard specification for labelling of plastics designed to be aerobically composted in municipal or industrial facilities | Determine if plastics will compost satisfactorily, and establish requirements for identifying items made from plastics or polymers, as “compostable in aerobic municipal and industrial composting facilities” |
ASTM D5338-15 | ASTM | Standard test method for determining aerobic biodegradation of plastic materials under controlled composting conditions, incorporating thermophilic temperatures | Determines the degree and rate of aerobic biodegradation of plastic materials on exposure to a controlled-composting environment under laboratory conditions, at thermophilic temperatures |
ASTM D6868-19 | ASTM | Standard specification for labelling of end items that incorporate plastics and polymers as coatings or additives with paper and other substrates designed to be aerobically composted in municipal or industrial facilities | Determine if end items (including packaging) which use plastics and polymers as coatings or binders will compost satisfactorily, in large scale aerobic municipal or industrial composting where maximum throughput is a high priority and where intermediate stages of plastic biodegradation must not be visible to the end user for aesthetic reasons |
ASTM D6954-18 | ASTM | Standard guide for exposing and testing plastics that degrade in the environment by a combination of oxidation and biodegradation | Compare and rank the controlled laboratory rates of degradation and degree of physical property losses of polymers by thermal and photooxidation processes as well as the biodegradation and ecological impacts in defined applications and disposal environments after degradation |
ASTM D5988-18 | ASTM | Standard test method for determining aerobic biodegradation of plastic materials in soil | Under laboratory conditions, determine the degree and rate of aerobic biodegradation of plastic materials, including formulation additives, in contact with soil |
ASTM D5526-18 | ASTM | Standard test method for determining anaerobic biodegradation of plastic materials under accelerated landfill conditions | Determine the degree and rate of anaerobic biodegradation of plastic materials in an accelerated-landfill test environment |
ASTM D7475-11 | ASTM | Standard test method for determining the aerobic degradation and anaerobic biodegradation of plastic materials under accelerated bioreactor landfill conditions | Determine the degree and rate of aerobic degradation (as indicated by loss of tensile strength, molecular weight, possibly resulting in disintegration and fragmentation) and anaerobic biodegradation of plastic materials in an accelerated bioreactor landfill test environment |
ASTM D6691-17 | ASTM | Standard test method for determining aerobic biodegradation of plastic materials in the marine environment by a defined microbial consortium or natural sea water Inoculum | Under controlled laboratory conditions, assess the rate and degree of aerobic biodegradation of plastics exposed to marine microorganisms |
ASTM D5511-18 | ASTM | Standard test method for determining anaerobic biodegradation of plastic materials under high-solids anaerobic-digestion conditions | Determine the rate and degree of anaerobic biodegradability of plastic products when placed in a high-solids anaerobic digester |
ASTM D7444-18a | ASTM | Standard practice for heat and humidity aging of oxidatively degradable plastics | Test the oxidative degradation characteristics of plastics that degrade in the environment under atmospheric pressure and thermal and humidity simulations |
ASTM WK41850 | ASTM | New Test Method for Determining the rate and extent of plastics biodegradation in an anaerobic laboratory environment under accelerated conditions | Laboratory assessment of the extent and rate of biodegradation of plastics in a simulated landfill environment |
标准号 Standard number | 机构 Institution | 名称 Name | 评估目标 Assessment objectives |
---|---|---|---|
EN 13432 | CEN | Packaging-Requirements for packaging recoverable through composting and biodegradation-Test scheme and evaluation criteria for the final acceptance of packaging | Determine the compostability and anaerobic treatability of packaging and packaging materials |
EN 14995 | CEN | Plastics-Evaluation of compostability-Test scheme and specifications | Determine the compostability or anaerobic treatability of plastic materials by addressing four characteristics: (1) Biodegradability, (2) Disintegration during biological treatment, (3) Effect on the biological treatment process and (4) effect on the quality of the resulting compost |
EN/ISO 20200 | CEN/ISO | Plastics-Determination of the degree of disintegration of plastic materials under simulated composting conditions in a laboratory-scale test | Determine the degree of disintegration of plastic materials in a pilot-scale aerobic composting test under defined conditions |
EN 14045 | CEN | Packaging-Evaluation of the disintegration of packaging materials in practical oriented tests under defined composting conditions | Measure the biodegradability of packaging materials that are mixed with biowaste and spontaneously composted for 12 weeks in practical oriented composting conditions |
EN 14046 | CEN | Packaging-Evaluation of the ultimate aerobic biodegradability of packaging materials under controlled composting conditions-Method by analysis of released carbon dioxide | Evaluate the ultimate aerobic biodegradability of packaging materials based on organic compounds under controlled composting conditions by measurement of released carbon dioxide at the end of the test |
EN/ISO 14855-1 | CEN/ISO | Determination of the ultimate aerobic biodegradability of plastic materials under controlled composting conditions- Method by analysis of evolved carbon dioxide-Part 1: General method | Determine the ultimate aerobic biodegradability of plastics, based on organic compounds, under controlled composting conditions by measurement of the amount of carbon dioxide evolved and the degree of disintegration of the plastic at the end of the test. The test method is designed to yield the percentage conversion of the carbon in the test material to evolved carbon dioxide as well as the rate of conversion |
EN/ISO 14855-2 | CEN/ISO | Determination of the ultimate aerobic biodegradability of plastic materials under controlled composting conditions- Method by analysis of evolved carbon dioxide-Part 2: Gravimetric measurement of carbon dioxide evolved in a laboratory-scale test | Determine the ultimate aerobic biodegradability of plastic materials under controlled composting conditions. The method is designed to yield an optimum rate of biodegradation by adjusting the humidity, aeration and temperature of the composting vessel |
EN 17033 | CEN | Plastics Biodegradable mulch films for use in agriculture and horticulture Requirements and test methods | The latest standard to evaluate the biodegradability of biodegradable mulch films |
Table 3 International and European standards for evaluating degradability of plastics under composting conditions
标准号 Standard number | 机构 Institution | 名称 Name | 评估目标 Assessment objectives |
---|---|---|---|
EN 13432 | CEN | Packaging-Requirements for packaging recoverable through composting and biodegradation-Test scheme and evaluation criteria for the final acceptance of packaging | Determine the compostability and anaerobic treatability of packaging and packaging materials |
EN 14995 | CEN | Plastics-Evaluation of compostability-Test scheme and specifications | Determine the compostability or anaerobic treatability of plastic materials by addressing four characteristics: (1) Biodegradability, (2) Disintegration during biological treatment, (3) Effect on the biological treatment process and (4) effect on the quality of the resulting compost |
EN/ISO 20200 | CEN/ISO | Plastics-Determination of the degree of disintegration of plastic materials under simulated composting conditions in a laboratory-scale test | Determine the degree of disintegration of plastic materials in a pilot-scale aerobic composting test under defined conditions |
EN 14045 | CEN | Packaging-Evaluation of the disintegration of packaging materials in practical oriented tests under defined composting conditions | Measure the biodegradability of packaging materials that are mixed with biowaste and spontaneously composted for 12 weeks in practical oriented composting conditions |
EN 14046 | CEN | Packaging-Evaluation of the ultimate aerobic biodegradability of packaging materials under controlled composting conditions-Method by analysis of released carbon dioxide | Evaluate the ultimate aerobic biodegradability of packaging materials based on organic compounds under controlled composting conditions by measurement of released carbon dioxide at the end of the test |
EN/ISO 14855-1 | CEN/ISO | Determination of the ultimate aerobic biodegradability of plastic materials under controlled composting conditions- Method by analysis of evolved carbon dioxide-Part 1: General method | Determine the ultimate aerobic biodegradability of plastics, based on organic compounds, under controlled composting conditions by measurement of the amount of carbon dioxide evolved and the degree of disintegration of the plastic at the end of the test. The test method is designed to yield the percentage conversion of the carbon in the test material to evolved carbon dioxide as well as the rate of conversion |
EN/ISO 14855-2 | CEN/ISO | Determination of the ultimate aerobic biodegradability of plastic materials under controlled composting conditions- Method by analysis of evolved carbon dioxide-Part 2: Gravimetric measurement of carbon dioxide evolved in a laboratory-scale test | Determine the ultimate aerobic biodegradability of plastic materials under controlled composting conditions. The method is designed to yield an optimum rate of biodegradation by adjusting the humidity, aeration and temperature of the composting vessel |
EN 17033 | CEN | Plastics Biodegradable mulch films for use in agriculture and horticulture Requirements and test methods | The latest standard to evaluate the biodegradability of biodegradable mulch films |
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